The vast majority of cup closures are made from various types of plastic polymers, each offering distinct properties:
Polystyrene (PS): Historically, PS has been a very common material for lid covers, particularly for hot beverages. It's inexpensive, easy to mold, and provides good insulation. You'll often find PS lids on coffee cups, characterized by their brittle feel and the distinct "click" when snapped into place. While convenient, PS is not widely recycled in many areas, leading to environmental concerns.
Polypropylene (PP): PP is gaining popularity for beverage toppers due to its versatility and improved recyclability compared to PS. It's more flexible and durable, making it less prone to cracking. PP lids are commonly used for both hot and cold beverages, including those with straws or sip-through openings. Its higher heat resistance also makes it suitable for microwaveable applications.
Polyethylene Terephthalate (PET): Primarily used for cold drink cups, PET is also employed for container caps when clarity is desired. PET lids offer excellent transparency, allowing consumers to see the beverage inside. They are lightweight and strong, but their use is generally limited to cold applications as they can deform under high heat. PET is widely recycled, often alongside PET bottles.
Polylactic Acid (PLA): As sustainability becomes a driving force, PLA is emerging as an eco-friendly alternative for disposable drink lids. PLA is a bioplastic derived from renewable resources like corn starch or sugarcane. It is compostable under industrial composting conditions, offering a biodegradable solution to plastic waste. However, PLA has a lower heat tolerance than traditional plastics, limiting its use primarily to cold beverages or specific warm applications.
Low-Density Polyethylene (LDPE): While less common for rigid lids, LDPE might be found in flexible or film-based cup seals, often used for sealing individual servings of condiments or desserts. It's known for its flexibility and excellent moisture barrier properties.

Several factors dictate which plastic polymer is selected for cup toppers:
Beverage Temperature: Hot beverages require materials with higher heat resistance (PS, PP), while cold drinks can utilize less heat-tolerant options (PET, PLA).
Durability and Flexibility: The need for a rigid, snap-on lid versus a more flexible, press-fit design influences the choice between materials like PS and PP.
Clarity: For visually appealing beverages, transparent materials like PET are preferred.
Cost-Effectiveness: The economics of production play a significant role, with PS generally being the most economical option.
Environmental Considerations: The growing demand for sustainable solutions is driving the adoption of recyclable materials (PP, PET) and compostable bioplastics (PLA).
Functionality: Specialized features like straw holes, sip-through openings, or recloseable designs can also influence material selection and molding processes.
It's also worth noting that cup coverings are not always made of a single, pure polymer. Additives might be incorporated to enhance properties like:
Impact resistance: To prevent cracking or breaking.
Colorants: For aesthetic purposes or branding.
UV stabilizers: To prevent degradation from sunlight.
Anti-static agents: To reduce static cling.
In some cases, a thin coating might be applied to the lid closure to improve its seal, provide a barrier, or enhance its feel.
The seemingly simple plastic cup lid is, in fact, a product of sophisticated material science and engineering. As consumer preferences and environmental regulations evolve, we can expect to see continued innovation in the materials and designs of these essential drink covers, with a growing emphasis on sustainability and functionality.